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Of note, on contrast to enzymes, enantioselective introduction of a proton to transient enediol intermediate via synthetic route might be extremely challenging to control it in terms of enantioselectivity due to the small size of the proton 3,7,8,9,10,11
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Although unnatural base pairs also play a significant role in the site-specific insertion of ncAAs, given the relative independence and criticality of this area, and the recent reviews 12 that have extensively explored it, this review will not delve into this aspect further
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