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Overall, the iodoacetamide alkyne ( 23 ) has the highest proteomic reactivity, followed by 21 α-thiochloroacetamide, 22 α-thiofluoroacetamide, 19 α-chloroacetamide and 20 α-fluoroacetamide, respectively (Fig
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1) ([M + H] + = 401.2071, Δ = 1.7 ppm) based on comparison of NMR, ECD, and mass spectrometry data with literature values 23,24,25,26 (Table S2, Figure S1 and S2)
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